TY - JOUR
T1 - A biorefinery strategy for spent industrial ginger waste
AU - Gao, Yang
AU - Ozel, Mustafa Z.
AU - Dugmore, Tom
AU - Sulaeman, Allyn
AU - Matharu, Avtar S.
N1 - Funding Information:
We would like to thank Dr Meg Stark at the Imaging and Cytometry Lab, Bioscience Technology Facility, University of York for carrying out TEM imaging and Dr Graeme McAllister for carrying out CHN analysis. APS acknowledges the Kementerian Keuangan Republik Indonesia for a Lembaga Pengelola Dana Pendidikan (LPDP) Scholarship to study for a Phd under the supervision of ASM. ASM EPSRC (Whole systems understanding of unavoidable food supply chain wastes for re-nutrition EP/P008771/1) for funding TD for Postdoctoral study.
Publisher Copyright:
© 2020 Elsevier B.V.
PY - 2021/1/5
Y1 - 2021/1/5
N2 - An integrated biorefinery approach using spent industrial ginger waste for resource recovery is reported. Valuable products including ginger oil, starch, microfibrillated cellulose (MFC), bio-oil and hydrochar were obtained. Approximately 4 % ginger oil, with a profile similar to commercial ginger oil, can be recovered via Soxhlet or Supercritical CO2 + 10 %EtOH extraction. The oil-free ginger residues were processed using two microwave techniques: starch, MFC and sugar-rich hydrolysates were firstly gained through hydrothermal microwave processing (120–200 °C in water alone), whilst chemical-rich bio-oils and energy-dense hydrochar (20–24.5 MJ kg−1) were obtained via conventional microwave pyrolysis (220–280 °C). The ginger MFC exhibited increased propensity to form microfibrillated cellulose (as evidenced by Transmission Electron Microscopy) with increasing temperature. Nanocrystalline cellulose was produced at the highest processing temperature (200 °C). These changes are commensurate with the leaching and decomposition of the amorphous regions within cellulose. The molecules and materials isolated have further downstream applications and, thus, compared to current low value resolution methods (dumping, burning or animal feed), spent industrial ginger waste is a significant resource for consideration within a biorefinery concept.
AB - An integrated biorefinery approach using spent industrial ginger waste for resource recovery is reported. Valuable products including ginger oil, starch, microfibrillated cellulose (MFC), bio-oil and hydrochar were obtained. Approximately 4 % ginger oil, with a profile similar to commercial ginger oil, can be recovered via Soxhlet or Supercritical CO2 + 10 %EtOH extraction. The oil-free ginger residues were processed using two microwave techniques: starch, MFC and sugar-rich hydrolysates were firstly gained through hydrothermal microwave processing (120–200 °C in water alone), whilst chemical-rich bio-oils and energy-dense hydrochar (20–24.5 MJ kg−1) were obtained via conventional microwave pyrolysis (220–280 °C). The ginger MFC exhibited increased propensity to form microfibrillated cellulose (as evidenced by Transmission Electron Microscopy) with increasing temperature. Nanocrystalline cellulose was produced at the highest processing temperature (200 °C). These changes are commensurate with the leaching and decomposition of the amorphous regions within cellulose. The molecules and materials isolated have further downstream applications and, thus, compared to current low value resolution methods (dumping, burning or animal feed), spent industrial ginger waste is a significant resource for consideration within a biorefinery concept.
KW - Biorefinery
KW - Ginger oil
KW - Microfibrillated cellulose
KW - Microwaves
KW - Spent industrial ginger
UR - http://www.scopus.com/inward/record.url?scp=85087758261&partnerID=8YFLogxK
U2 - 10.1016/j.jhazmat.2020.123400
DO - 10.1016/j.jhazmat.2020.123400
M3 - Article
C2 - 32763696
AN - SCOPUS:85087758261
SN - 0304-3894
VL - 401
JO - Journal of Hazardous Materials
JF - Journal of Hazardous Materials
M1 - 123400
ER -