Investigation of cyanide ions adsorbed on platinum and palladium coated silver island films by surface-enhanced Raman spectroscopy

E. Hesse; J.A. Creighton

doi:10.1016/S0009-2614(99)00188-8

Investigation of cyanide ions adsorbed on platinum and palladium coated silver island films by surface-enhanced Raman spectroscopy

E. Hesse, J.A. Creighton

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Bimetallic films prepared by vacuum-depositing platinum onto silver island films have been evaluated for surface-enhanced Raman scattering (SERS), using CN− as the adsorbate. For platinum overlayers with mean thickness corresponding to 1–2 monolayers the spectrum is dominated by a band consistent with either CN− adsorbed at the platinum surface or with Pt(CN)42−. For thinner platinum overlayers, changes in the spectra due to migration of CN− from Ag(CN)2− to the surface platinum atoms were observed during the first few minutes of laser illumination. Similar palladium-on-silver films showed a prominent SERS band assigned to surface Pd(CN)42−.

Original language	English
Pages (from-to)	101-106
Journal	Chemical Physics Letters
Volume	303
Issue number	1-2
DOIs	https://doi.org/10.1016/S0009-2614(99)00188-8
Publication status	Published - 1999

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title = "Investigation of cyanide ions adsorbed on platinum and palladium coated silver island films by surface-enhanced Raman spectroscopy",

abstract = "Bimetallic films prepared by vacuum-depositing platinum onto silver island films have been evaluated for surface-enhanced Raman scattering (SERS), using CN− as the adsorbate. For platinum overlayers with mean thickness corresponding to 1–2 monolayers the spectrum is dominated by a band consistent with either CN− adsorbed at the platinum surface or with Pt(CN)42−. For thinner platinum overlayers, changes in the spectra due to migration of CN− from Ag(CN)2− to the surface platinum atoms were observed during the first few minutes of laser illumination. Similar palladium-on-silver films showed a prominent SERS band assigned to surface Pd(CN)42−.",

author = "E. Hesse and J.A. Creighton",

note = "Original article can be found at: http://www.sciencedirect.com/science/journal/00092614 Copyright Elsevier B.V. DOI: 10.1016/S0009-2614(99)00188-8 [Full text of this article is not available in the UHRA]",

year = "1999",

doi = "10.1016/S0009-2614(99)00188-8",

language = "English",

volume = "303",

pages = "101--106",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "1-2",

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TY - JOUR

T1 - Investigation of cyanide ions adsorbed on platinum and palladium coated silver island films by surface-enhanced Raman spectroscopy

AU - Hesse, E.

AU - Creighton, J.A.

N1 - Original article can be found at: http://www.sciencedirect.com/science/journal/00092614 Copyright Elsevier B.V. DOI: 10.1016/S0009-2614(99)00188-8 [Full text of this article is not available in the UHRA]

PY - 1999

Y1 - 1999

N2 - Bimetallic films prepared by vacuum-depositing platinum onto silver island films have been evaluated for surface-enhanced Raman scattering (SERS), using CN− as the adsorbate. For platinum overlayers with mean thickness corresponding to 1–2 monolayers the spectrum is dominated by a band consistent with either CN− adsorbed at the platinum surface or with Pt(CN)42−. For thinner platinum overlayers, changes in the spectra due to migration of CN− from Ag(CN)2− to the surface platinum atoms were observed during the first few minutes of laser illumination. Similar palladium-on-silver films showed a prominent SERS band assigned to surface Pd(CN)42−.

AB - Bimetallic films prepared by vacuum-depositing platinum onto silver island films have been evaluated for surface-enhanced Raman scattering (SERS), using CN− as the adsorbate. For platinum overlayers with mean thickness corresponding to 1–2 monolayers the spectrum is dominated by a band consistent with either CN− adsorbed at the platinum surface or with Pt(CN)42−. For thinner platinum overlayers, changes in the spectra due to migration of CN− from Ag(CN)2− to the surface platinum atoms were observed during the first few minutes of laser illumination. Similar palladium-on-silver films showed a prominent SERS band assigned to surface Pd(CN)42−.

U2 - 10.1016/S0009-2614(99)00188-8

DO - 10.1016/S0009-2614(99)00188-8

M3 - Article

SN - 0009-2614

VL - 303

SP - 101

EP - 106

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

ER -

Investigation of cyanide ions adsorbed on platinum and palladium coated silver island films by surface-enhanced Raman spectroscopy

Abstract

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